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Mpali follows the story of Mr Nguzu, a polygamist married to seven women, Junza (the first wife), Mwiza (the second wife), Monde (the third wife), Tombi (the fourth wife), Shupiwe (the fifth wife, Tamara (the sixth wife) and lastly Nancy (the seventh wife). The family is still together trying to make a living and working hard to remain united despite numerous factors working against them.