Terrance and Raylee
Raylene had car trouble one day, and called a friend who she thought could help her sort it out. Instead of coming himself, the friend sent Terrence over to help Raylee out of her pickle, the same Terrence who would one day become her husband. Being the superhero he was, Terrence sorted Raylene's car out, and they said their goodbyes.
However, what he didn't know was that he had made quite an impression on Raylene, who instantly developed a crush on him. The feeling was mutual, as the next Friday, as she and her friend were getting ready to go out that evening, Terrence pulled up outside her house. She invited him in, and they ended up taking Terrence along on their night out.